Main Article Content
Abstract
Lindur fruit (Bruguiera gymnorrhiza L.) is widely available in Indonesia and has a high carbohydrate content, so it has the potential to be developed as a new source of energy and starch. So far, the use of lindur fruit is still limited to substitute rice and snacks. Therefore, it is necessary to make efforts to increase the utilization of lindur fruit by processing it into lindur starch and its derivatives (modified starch). The properties of lindur starch need to be improved in order to have wider uses in the food and non-food industries. The purpose of this study was to modify lindur starch by oxidation using NaOCl with ferrous sulfate as a catalyst. In this study, the effect of sodium hypochlorite concentration (2%, 4%, 6%, and 8%) and ferrous sulfate concentration (0%, 0.1%, 0.2%, and 0.3%) on the physicochemical characteristics of starch was studied. the resulting oxidized leachate and determined the optimal conditions. The results showed that all the variables studied affected the oxidation reaction of lindur starch. Oxidation at 4% NaOCl concentration and 0.2% ferrous sulfate concentration was able to produce the best values for carboxyl content, solubility, and swelling.
Article Details
References
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References
Anonym.1997. Modified Starches. JECFA
Ariyanti, D., Budiyati, C.S., and Kumoro, A.C. 2014. Modifikasi Tepung Umbi Talas Bogor (Colocasia esculentum (L) schott)dengan Teknik Oksidasi sebagai Bahan Pangan Pengganti Tepung Terigu. Reaktor 15(1) : 1-9. https://doi.org/10.14710/reaktor.15.1.1-9
BeMiller, J. dan Whistler, R. 2009. Starch : Chemistry dan Technology. USA : Elsevier. 151, 343.
Budiyati, C.S., Kumoro, A.C., Ratnawati, R., dan Retnowati, D.S. 2016. Modifikasi Pati Sukun (Artocarpus Altilis) dengan Teknik Oksidasi Menggunakan Hidrogen Peroksida Tanpa Katalis. TEKNIK, 37 (1) : 32-40. https://doi.org/10.14710/teknik.v37i1.9832
Chan, H.T., Bhat, R., and Karim, A.A., (2009), Physicochemical and Functional Properties of Ozone-Oxidized Starch. Journal of Agricultural and Food Chemistry, 57, pp. 5965–5970.
Chan H, Leh CP, Bhat R, Senan C, Williams PA, Karim AA. 2011. Molecular structure, rheological and thermal characteristics of ozone-oxidized starch. Food Chem 126: 1019–1024. DOI: 10.1016/ j.foodchem.2010.11.113.
Fatchuri, A. and Wijayatiningrum, F.N. 2009. Modifikasi Cassava Starch Dengan Proses Oksidasi Sodium Hypoclorite Untuk Industri Kertas. In: Seminar Tugas Akhir S1 Teknik Kimia Undip 2009", Jurusan Teknik Kimia Undip, Semarang (Unpublished)
Fitria, E., Hariyadi, P., Andarwulan, N., Triana, R.N. 2018. Sifat Fisikokimia Pati Sagu Termodifikasi dengan Metode Oksidasi Menggunakan Natrium Hipoklorit (Physicochemical Properties of Oxidized Sago Starch Using Sodium Hypochlorite). Jurnal Mutu Pangan 5(2) : 100-108
Garrido LH, Schnitzler E, Zortea MEB, Rocha TS, Demiate IM. 2012. Physischochemical properties of cassava starch oxidized by sodium hypochlorite. J Food Sci Technol DOI: 10.1007/ s13197-012-0794- 9.
Gumul D, Krystyjan M, Buksa K, Ziobro R, Zieba T. 2013. The influence of oxidation, extrusion, and oxidation/extrusion on physicochemical properties of potato starch. Starch/Starke 65: 1-9. DOI: 10.100 2/star.201300069.
Kainuma, K., Odat, T., & Cuzuki, S. 1967. Study of Starch Phosphates Monoesters. Journal of Technology Society Starch, 14, 24 - 28.
Leach, H. W., Mc Cowen, L. D., & Schoch, T. J. 1959. Structure of the Starch Granules. In: Swelling and Solubility Patterns of Various Starches. Cereal Chemistry, 36, 534 – 544.
Rahardian, A., Prasetyo, L. B., Setiawan, Y., & Wikantika, K. 2019. Tinjauan historis data dan informasi luas mangrove Indonesia. Media Konservasi, 24(2), 163–178.
Rosulva, I., Hariyadi, P., Budijanto, S., & Sitanggang, A.B. 2021. Potential Of Mangrove Fruit As An Alternative Food Source. Jurnal Teknologi Hasil Pertanian. 14(2), 131-150. DOI: https://doi.org/10.20961/jthp.v14i2.55509
Sadana. D. 2007. Buah Aibon di Biak Timur Mengandung Karbohidrat Tinggi. Situs Resmi Pemda Biak Num for news_.htm.
Sarungallo, Z.L. & Santoso, B. 2007. Sifat Fisik dan Komposisi Kimia Buah Aibon (Brugueira gymnorhiza L.) pada Berbagai Tingkat Kematangan. J. Bionatura. 9: 83-92.
Sarungallo, Z. L., Santoso, B., & Tethool, E. F. 2010. Sifat fisikokimia dan fungsional pati buah aibon (Brugueira gymnorhiza L.). Jurnal Natur Indonesia, 12(2), 156–162. DOI: http://dx.doi.org/10.31258/jnat.12.2.156-162
Tharanathan., R.N. 2005. Starch-Value Addition by Modification. Critical Reviews in Food Science and Nutrition. Vol 45 : 371-384. Copyright Taylor and Francis Inc. ISSN: 1040-8398. DOI: 10.1080/10408390590967702
Tethool, E.F., Jading, A. dan Santoso, B. 2012. Pengaruh Konsentrasi Hidrogen Peroksida dan Irradiasi Ultraviolet terhadap Sifat Fisikokimia dan Baking Expansion Pati Sagu. Prosiding InSINas. Bandung
Tolvanen, P., Sorokin, A.B., Mäki-Arvela, P.,Murzin, D.Y., and Tapio Salmi, T. 2013. Oxidation of Starch by H2O2 in the Presence of Iron Tetrasulfophthalocyanine Catalyst: The Effect of Catalyst Concentration, pH, Solid−Liquid Ratio, and Origin of Starch. Industrial Engineering Chemistry Research. 52 (27) : 9351-9358. DOI:10.1021/ie4003969
Wang, Y.J. and Wang, L. 2003. Physicochemical properties of common and waxy corn starches oxidized by different levels of sodium hypochlorite. Carbohydrate Polymers. 52 (3) : 207-217. DOI: 10.1016/S0144-8617(02)003041
Xiao, H., Lin Q., Liu G, Yu, F. 2012. A comparative study of the characteristics of cross-linked. oxidized and dual-modified rice starches. Molecules 17 (9) : 10946- 10957. https://doi.org/10.3390/molecules170910946